Elegant: The 37-year-old looked sophisticated in the blue dress, which she paired with a tailored cream blazer and dainty white belt
Kaley at least got it right with her stylish accessories - pointy black heels and a leopard-print clutch.
The California native wore her platinum blonde hair in loose waves over her shoulders, and opted for a smokey eye and nude lips.
The actresses were joined by their The Big Bang Theory costars, including Johnny Galecki, Kunal Nayyar, and Jim Parsons, who was dapper in a slick suit.
Black as night: NCIS actress Pauley Perrette opted for an all-black ensemble of a short dress, tights and flat boots
Also at the event was NCIS actress Pauley Perrette, who was sultry in an all-black ensemble that consisted of a short dress, tights and flat leather boots.
The 43-year-old wore her signature raven mane in a ponytail, her long blunt fringe framing her pretty face.
The bakery shop owner displayed her forearm tattoos and added a pop of colour to the somber outfit with a slick of deep red lipstick.
Lady in leather: The Big Bang Theory star Melissa Rauch poured her curves into skintight leather trousers for the event
Cool dude: The Big Bang Theory star Johnny Galecki also wore leather in the form of a biker jacket, which he paired with a waistcoat and smart grey trousers
Laid-back style: The Big Bang Theory's Kunal Nayyar was dressy casual in a blue shirt, dark blue trousers and suede boots
Book worm: Simon Helberg went with an academic look of a tweed blazer and tie
Dapper: Jim Parsons went against the grain and donned a sleek suit for the event
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