She plays the geeky foil to Kaley Cuoco's sexy character Penny in The Big Bang Theory.
But the roles were reversed as Mayim Bialik showed herself to be the stylish one on Wednesday night.
The 37-year-old actress was fresh-faced and sophisticated in a floaty aquamarine dress while 27-year-old Kaley was all but enveloped by her dowdy white dress at The Big Bang Theory TV Series presentation at the Paley Center in Los Angeles.
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Brunette versus blonde: Mayim Bialik looked elegant in an aquamarine dress while her The Big Bang Theory costar was a fashion miss in a shapelss white dress at the PaleyFest at the Paley Center in Los Angeles on Wednesday night
The Big Bang Theory stars were a lesson in opposites as they posed on the red carpet at the annual Paley Television Festival, a series of panels featuring the cast and crew of some of television's biggest shows.
Mayim showed off her slender figure in the knee-length blue frock, nipping in her waist with a dainty white belt.
The mother-of-two covered up with a tailored cream blazer and added an edgy touch with snakeskin heels.
She wore her brown hair in an elegant high bun and kept her makeup simple, highlighting her brown eyes with a smudge of smokey eyeshadow and her lips with a glossy peach hue.
Kaley, meanwhile, hid her slim physique in the white dress with black trimming, which hung off her frame like a potato sack.
The blonde actress stood somewhat awkwardly as she posed on the red carpet, perhaps unsure of how best to show off her body in the shapeless shift.
Elegant: The 37-year-old looked sophisticated in the blue dress, which she paired with a tailored cream blazer and dainty white belt
Kaley at least got it right with her stylish accessories - pointy black heels and a leopard-print clutch.
The California native wore her platinum blonde hair in loose waves over her shoulders, and opted for a smokey eye and nude lips.
The actresses were joined by their The Big Bang Theory costars, including Johnny Galecki, Kunal Nayyar, and Jim Parsons, who was dapper in a slick suit.
Black as night: NCIS actress Pauley Perrette opted for an all-black ensemble of a short dress, tights and flat boots
Lady in leather: The Big Bang Theory star Melissa Rauch poured her curves into skintight leather trousers for the event
Also at the event was NCIS actress Pauley Perrette, who was sultry in an all-black ensemble that consisted of a short dress, tights and flat leather boots.
The 43-year-old wore her signature raven mane in a ponytail, her long blunt fringe framing her pretty face.
The bakery shop owner displayed her forearm tattoos and added a pop of colour to the somber outfit with a slick of deep red lipstick.
Cool dude: The Big Bang Theory star Johnny Galecki also wore leather in the form of a biker jacket, which he paired with a waistcoat and smart grey trousers
Laid-back style: The Big Bang Theory's Kunal Nayyar was dressy casual in a blue shirt, dark blue trousers and suede boots
Book worm: Simon Helberg went with an academic look of a tweed blazer and tie
Dapper: Jim Parsons went against the grain and donned a sleek suit for the event
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